Welcome to DU! The truly grassroots left-of-center political community where regular people, not algorithms, drive the discussions and set the standards. Join the community: Create a free account Support DU (and get rid of ads!): Become a Star Member Latest Breaking News General Discussion The DU Lounge All Forums Issue Forums Culture Forums Alliance Forums Region Forums Support Forums Help & Search

OKIsItJustMe

(19,938 posts)
Tue Mar 20, 2012, 07:33 PM Mar 2012

Greenhouse gas can find a home underground

http://web.mit.edu/newsoffice/2012/greenhouse-gas-in-aquifers-0320.html
[font face=Times, Times New Roman, Serif][font size=5]Greenhouse gas can find a home underground[/font]
[font size=4]New MIT analysis shows there’s enough room to safely store at least a century’s worth of U.S. fossil fuel emissions.[/font]

March 20, 2012

[font size=3]A new study by researchers at MIT shows that there is enough capacity in deep saline aquifers in the United States to store at least a century’s worth of carbon dioxide emissions from the nation’s coal-fired powerplants. Though questions remain about the economics of systems to capture and store such gases, this study addresses a major issue that has overshadowed such proposals.

The MIT team’s analysis — led by Ruben Juanes, the ARCO Associate Professor in Energy Studies in the Department of Civil and Environmental Engineering, and part of the doctoral thesis work of graduate students Christopher MacMinn PhD ’12 and Michael Szulczewski — is published this week in the Proceedings of the National Academy of Sciences.

Coal-burning powerplants account for about 40 percent of worldwide carbon emissions, so climate change “will not be addressed unless we address carbon dioxide emissions from coal plants,” Juanes says. “We should do many different things” such as developing new, cleaner alternatives, he says, “but one thing that’s not going away is coal,” because it’s such a cheap and widely available source of power.

Efforts to curb greenhouse gases have largely focused on the search for practical, economical sources of clean energy, such as wind or solar power. But human emissions are now so vast that many analysts think it’s unlikely that these technologies alone can solve the problem. Some have proposed systems for capturing emissions — mostly carbon dioxide from the burning of fossil fuels — then compressing and storing the waste in deep geological formations. This approach is known as carbon capture and storage, or CCS.

…[/font][/font]
http://dx.doi.org/10.1073/pnas.1115347109
25 replies = new reply since forum marked as read
Highlight: NoneDon't highlight anything 5 newestHighlight 5 most recent replies
Greenhouse gas can find a home underground (Original Post) OKIsItJustMe Mar 2012 OP
Gnurds! izquierdista Mar 2012 #1
Ah, good, let's just say business as usual for another 100 years. I just love it. NYC_SKP Mar 2012 #2
What exactly do you suggest we do? madokie Mar 2012 #3
I expect that we will continue on pretty much as we have, until we can't any more. GliderGuider Mar 2012 #4
I agree with this madokie Mar 2012 #5
The stars have aligned! guardian Mar 2012 #8
OK, now I'm officially frightened! GliderGuider Mar 2012 #9
Maybe we will share a bottle of wine over it one day. n/t guardian Mar 2012 #10
Heaven's no. In fact, next Thursday I commission a 500kW solar plant.... NYC_SKP Mar 2012 #6
I was simply stating that building more nuke plants is not acceptable to me madokie Mar 2012 #7
Hi, sry! NYC_SKP Mar 2012 #11
I agree with that madokie Mar 2012 #14
Whenever CCS rolls up... Dead_Parrot Mar 2012 #12
What I don't get is madokie Mar 2012 #13
My guess is... Dead_Parrot Mar 2012 #15
I don’t think gasification is nearly enough OKIsItJustMe Mar 2012 #16
I think D_P has it figured out madokie Mar 2012 #17
I think I'd like to see the numbers... Dead_Parrot Mar 2012 #18
How Coal Gasification Power Plants Work OKIsItJustMe Mar 2012 #19
That diagram makes my point quite well Dead_Parrot Mar 2012 #22
I guess I should have included the entire article OKIsItJustMe Mar 2012 #24
I'm lost at the coke part madokie Mar 2012 #20
All I know is that the carbon XemaSab Mar 2012 #21
With wood, you *could* echo the process to make charcoal.... Dead_Parrot Mar 2012 #23
Spam deleted by OKNancy (MIR Team) bharatbook Mar 2012 #25
 

izquierdista

(11,689 posts)
1. Gnurds!
Tue Mar 20, 2012, 07:41 PM
Mar 2012

There's enough room in the soil if you turn biomass into biochar and bury it. Did you think about that, tools? And how much energy is it going to take to compress and pump that gas underground?

 

NYC_SKP

(68,644 posts)
2. Ah, good, let's just say business as usual for another 100 years. I just love it.
Tue Mar 20, 2012, 10:19 PM
Mar 2012

So better to bury it than to not, but better to not create it at all.

I wonder what the constraints are, what the likelihood of actually being able to effectively use even 1% of this theoretical capacity.

I hate the way that CCS schemes are preventing so many people from taking carbon consequences more seriously.

Blechhh!

madokie

(51,076 posts)
3. What exactly do you suggest we do?
Wed Mar 21, 2012, 07:40 AM
Mar 2012

building more nuke plants is not the answer and you should know that so hopefully that won't be your answer to my question of what exactly do you suggest we do
To each his own and this is my opinion

 

GliderGuider

(21,088 posts)
4. I expect that we will continue on pretty much as we have, until we can't any more.
Wed Mar 21, 2012, 08:16 AM
Mar 2012

We won't bury CO2, and we won't stop producing it. We won't build many more nukes, electric cars won't take over the market, we won't put PV on every rooftop in sight. We may do a little of each of these things here and there (globally speaking) but until circumstances make it impossible to continue, politics and social inertia will prevent any significant proactive shift in our activities.

The first shift in circumstances will probably be a global economic crash.
The second concurrent factor will be demand destruction in oil consumption driven by shortages and rising relative prices.
The third will likely be spreading social instability due to a combination of the economic crash and weather events driven by climate change.

As kristopher educated me a while ago, anthropologist Marvin Harris makes a good case that cultural change is driven by the state of the underlying infrastructure (part of which is the physical environment and resource base), not the reverse. If Harris is right, then all the "suggestions" in the world about what we should or shouldn't do are, in the end, pretty much moot. We will start to change only when economics and climate change affect enough important people.

This means there is probably a population bottleneck coming.

madokie

(51,076 posts)
5. I agree with this
Wed Mar 21, 2012, 08:56 AM
Mar 2012

We should let solutions drive our efforts, if that makes any sense to you. As it is today we let the bottom line drive what we do, well some anyway. In my personal life I try to find a balance between what I want, what I need and what I should do. Most times what actually happens is a product, if you will, of the three. A large part of what is driving all this GHG's is our throw away habits. So many times so many people simply buy because its something new and many times the new is mostly in looks and not so much in quality.
The corporate pushes this mem off on us as its a way to increase their bottom line.

I have a lot of respect for both you and Kris as you both seem to try your best to engage in reasoned debate rather than knee jerk reaction that I and others here are so guilty of so many times.
Peace

 

NYC_SKP

(68,644 posts)
6. Heaven's no. In fact, next Thursday I commission a 500kW solar plant....
Wed Mar 21, 2012, 09:03 AM
Mar 2012

...for which I wrote the RFP and handled all negotiations.

I said nothing about nuke plants and am not sure why you even went there?



I suggest that we expose the research for what it is: pie in the sky.

"there’s enough room to safely store at least a century’s worth of U.S. fossil fuel emissions"

there's also enough room on Mars.

madokie

(51,076 posts)
7. I was simply stating that building more nuke plants is not acceptable to me
Wed Mar 21, 2012, 10:37 AM
Mar 2012

business of usual is part nuclear and thats where my reply on that came from.
The part about mars I'm not so sure of what you're getting at. Maybe you forgot something

Congratulations on what you are doing. Its much more than what I'm doing thats for sure and I applaud you for it.
Peace

 

NYC_SKP

(68,644 posts)
11. Hi, sry!
Wed Mar 21, 2012, 10:04 PM
Mar 2012

It angers me, and you I'll bet, that they keep looking at ways to make coal or nukes friendly, when all the technology is already her.

I might have needed to us a sarcasm smiley or have been less angry in my reply.

Peace back to you, madokie!

madokie

(51,076 posts)
14. I agree with that
Thu Mar 22, 2012, 07:39 AM
Mar 2012

Some people are simply class acts and I'm happy to say I see you as one of them.

Dead_Parrot

(14,478 posts)
12. Whenever CCS rolls up...
Wed Mar 21, 2012, 11:18 PM
Mar 2012

I think of this article:

Drillers often inject CO2 into the ground to drive more oil out, but researchers conducting the U.S. Department of Energy-sponsored Frio Brine Pilot Experiment northeast of Houston, Texas, pumped 1600 tons of CO2 into the Frio Formation to see where the gas went and what it did. "We're the first looking in this huge detail so that we can see what's going on," says geochemist and lead study author Yousif Kharaka of the U.S. Geological Survey in Menlo Park, California. He and colleagues found that the CO2 dropped the pH of the formation's brine from a near-neutral 6.5 to 3.0, about as acid as vinegar. That change in turn dissolved "many, many minerals," says Kharaka, releasing metals such as iron and manganese. Organic matter entered solution as well, and relatively large amounts of carbonate minerals dissolved.
...
Geochemist Julio Friedmann of Stanford University is less concerned about corrosion eating away the seals on a sequestration site. "The crust of Earth is well configured to contain CO2," he says. He points to 80 U.S. oil fields injected with CO2 for up to 30 years. "We've seen no catastrophic failures." Nevertheless, the Frio results do "suggest an aspect of risk we hadn't considered before," says Friedmann. It is now obvious that if CO2 made it only so far as an overlying aquifer, he says, it could wreak havoc.

madokie

(51,076 posts)
13. What I don't get is
Thu Mar 22, 2012, 07:16 AM
Mar 2012

there is two ways to extract the energy from organic material such as coal, one is to burn it directly or gasify it then burn the gases which is about 20 plus percent hydrogen a much cleaner way to get that energy locked up in the coal with somewhere from 40 to 50 percent less co2 produced. What I don't get is why is it that whenever someone mentions gasifier everyone thinks of CCS. Just by gasifying coal you can save about half of the co2 being produced per unit of energy. There's all kinds of links about how gasifying is done and the results and over the years I've posted many of them only to be met with silence or scorn, depending on who and when I reply too.
I'm all for gasifying the coal but not for putting the easier to capture co2 in the ground, If you just let it go into the atmosphere there is about half as much as the present way of burning coal produces. I would like to see us move away from coal as it is so destructive in so many environmental ways but I'm not for adding to our nuclear fleet. The mining of uranium is very environmentally destructive also plus it has other issues that I'm concerned about.

Dead_Parrot

(14,478 posts)
15. My guess is...
Thu Mar 22, 2012, 02:35 PM
Mar 2012

...that since they are both technologies than make coal 'cleaner', they just get lumped together at the lobbyist/PR level by people who don't really think about it. Depending on the recipe, gasification can turn out coke, tar, phenol, and the syngas can go on to gas/diesel, DME, or of course just be fired for electricity: In theory, CCS could be applied to any of these streams (OK, a little tricky for some) but in practice it's just the syngas for electricity. It's enough, however, to let them say "We're burning coal and capturing the emissions!" while they flog coke through the back door.

OKIsItJustMe

(19,938 posts)
16. I don’t think gasification is nearly enough
Thu Mar 22, 2012, 03:41 PM
Mar 2012

Yes, it would be better to burn the coal more efficiently. However, we need to virtually eliminate carbon emissions (not just decrease them dramatically.)

So, assuming you’re doing the work to retrofit the coal industry to support gasification, why wouldn’t you attempt to capture the carbon at the same time?

madokie

(51,076 posts)
17. I think D_P has it figured out
Thu Mar 22, 2012, 04:33 PM
Mar 2012

I'm just saying that if they did that one thing, gasify, alone it would have made a big difference in where we are today since about 40 percent of our co2 pollution comes from burning coal. If we were using a cleaner process that would have to help.

I say we need to quit using coal as quickly as we can. With this glut of natural gas from fracking, that we don't like, it would be a better choice than to continue burning coal. I'm against fracking but if they're going to do it anyway it would be better to burn the gas here making our electric rather than burn coal. Right now Chesapeake Oil is negotiating with china to sell them LNG. We get the damage from fracking with out any of the benefits it could give us.

I agree that gasification alone is not enough but it would have bought us time. Either way its too late now, the horse is already out of the barn.

Dead_Parrot

(14,478 posts)
18. I think I'd like to see the numbers...
Thu Mar 22, 2012, 05:08 PM
Mar 2012

...on how the streams add up. Pulling out wildly innaccurate figures for purposes of illustration:

Say we have 100g of coal. We burn it, old school, for 100J of electricity and get 90g of CO2 and 10g of assorted shit.
So, .9g/J CO2.

Now lets say we gassify it to get 50g gas and 50g coke. We burn the gas for 80J of electricity and get 50g of CO2
So, .6g/J CO2. Cool, it's cleaner.
But we've also got this 50g coke we unload to a steel mill where it gets burned for 20J leaving 40g CO2 and 10g assorted shit. Ouch.

But hey, the electricity's cleaner!

Intuition tells me that processes like gasification aren't going to add to the embedded energy of the coal, nor reduce the embedded carbon. They can only turn it into a fun shell game that leaves us scratching our heads wondering where the pea went: I'm pretty sure it's there somewhere.

Of course, my intuition may be out of whack - but in that case, it'll take some hard numbers to convince me.

OKIsItJustMe

(19,938 posts)
19. How Coal Gasification Power Plants Work
Thu Mar 22, 2012, 05:37 PM
Mar 2012

(Please note, US Department of Energy information — copyright concerns are nil.)

http://fossil.energy.gov/programs/powersystems/gasification/howgasificationworks.html

[font face=Times, Times New Roman, Serif][font size=5]How Coal Gasification Power Plants Work[/font]

[font size=3]…

In Integrated Gasification Combined-Cycle (IGCC) systems, the syngas is cleaned of its hydrogen sulfide, ammonia and particulate matter and is burned as fuel in a combustion turbine (much like natural gas is burned in a turbine). The combustion turbine drives an electric generator. Exhaust heat from the combustion turbine is recovered and used to boil water, creating steam for a steam turbine-generator.

The use of these two types of turbines - a combustion turbine and a steam turbine - in combination, known as a "combined cycle," is one reason why gasification-based power systems can achieve high power generation efficiencies. Currently, commercially available gasification-based systems can operate at around 40% efficiencies; in the future, some IGCC systems may be able to achieve efficiencies approaching 60% with the deployment of advanced high pressure solid oxide fuel cells. (A conventional coal-based boiler plant, by contrast, employs only a steam turbine-generator and is typically limited to 33-40% efficiencies.)

Higher efficiencies mean that less fuel is used to generate the rated power, resulting in better economics (which can mean lower costs to ratepayers) and the formation of fewer greenhouse gases (a 60%-efficient gasification power plant can cut the formation of carbon dioxide by 40% compared to a typical coal combustion plant).

All or part of the clean syngas can also be used in other ways:
  • As chemical "building blocks" to produce a broad range of higher-value liquid or gaseous fuels and chemicals (using processes well established in today's chemical industry);

  • As a fuel producer for highly efficient fuel cells or perhaps in the future, hydrogen turbines and fuel cell-turbine hybrid systems;

  • As a source of hydrogen that can be separated from the gas stream and used as a fuel (for example, in the hydrogen-powered Freedom Car initiative) or as a feedstock for refineries (which use the hydrogen to upgrade petroleum products).
…[/font][/font]



OK, so conventional coal is 33-40% efficient.

Commercially available gasification-based systems can operate at around 40% efficiencies” (better, but not much better.)

IGCC may reach 60% efficiency perhaps achieving a 40% reduction in carbon emissions over conventional coal technology (much better, but a long way from carbon neutral.)

Dead_Parrot

(14,478 posts)
22. That diagram makes my point quite well
Thu Mar 22, 2012, 07:50 PM
Mar 2012

Your eye might catch the words "marketable solid byproducts", but it's tucked away in the left corner so doesn't dwell on it. It moves on to the bright colors on the right...

OKIsItJustMe

(19,938 posts)
24. I guess I should have included the entire article
Fri Mar 23, 2012, 08:26 AM
Mar 2012


Minerals components in the fuel, which don't gasify like carbon-based constituents leave the gasifier either as an inert glass-like slag or in a form useful to marketable solid products. A small fraction of the mineral matter is blown out of the gasifier as fly ash and requires removal downstream.

madokie

(51,076 posts)
20. I'm lost at the coke part
Thu Mar 22, 2012, 07:30 PM
Mar 2012

in the process I've studied and played with all that is left is a little ash but my experience with gasifiers is with wood as a feed stock. I simply figured that would be what would be left of the coal after the gasifying process.
So I'm all ears as to the coke. I'm not doubting just trying to learn something.

https://en.wikipedia.org/wiki/Coal_gasification#By-products
In this they mention that coke is a by product, knock me over with a soft sigh

http://www.fossil.energy.gov/programs/powersystems/gasification/ Here is an explanation of how a gasification power plant works and I wonder if maybe it should be required reading for this discussion

Dead_Parrot

(14,478 posts)
23. With wood, you *could* echo the process to make charcoal....
Thu Mar 22, 2012, 08:09 PM
Mar 2012

...but I know from experience charcoal making is a bitch, even if you're not trying to catch the gases - ending up with ash would be more likely . Run the process with coal and you'll get coke.

Possibly worth noting that the process was originally developed to get the coke out: It makes for cheap iron, and reliably coking coal was one of the key technologies of the industrial revolution. It wasn't until the 19th century we figured out the stuff going up the chimney was useful, too.

Now we've swung the other way and are trying to pretend the coke doesn't exist at all...

Response to OKIsItJustMe (Original post)

Latest Discussions»Issue Forums»Environment & Energy»Greenhouse gas can find a...