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Nanocrystals and Nickel Catalyst Substantially Improve Light-Based Hydrogen Production
http://www.rochester.edu/news/show.php?id=4892[font face=Serif][font size=5]Nanocrystals and Nickel Catalyst Substantially Improve Light-Based Hydrogen Production[/font]
November 8, 2012
[font size=3] Hydrogen is an attractive fuel source because it can easily be converted into electric energy and gives off no greenhouse emissions. A group of chemists at the University of Rochester is adding to its appeal by increasing the output and lowering the cost of current light-driven hydrogen-production systems.
The work was done by graduate students Zhiji Han and Fen Qiu, as part of a collaboration between chemistry professors Richard Eisenberg, Todd Krauss, and Patrick Holland, which is funded by the U.S. Department of Energy. Their paper will be published later this month (Nov. 23) in the journal Science.
The chemists say their work advances what is sometimes considered the "holy grail" of energy science—efficiently using sunlight to provide clean, carbon-free energy for vehicles and anything that requires electricity.
One disadvantage of current methods of hydrogen production has been the lack of durability in the light-absorbing material, but the Rochester scientists were able to overcome that problem by incorporating nanocrystals. "Organic molecules are typically used to capture light in photocatalytic systems," said Krauss, who has been working in the field of nanocrystals for over 20 years. "The problem is they only last hours, or, if you're lucky, a day. These nanocrystals performed without any sign of deterioration for at least two weeks."
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http://dx.doi.org/10.1126/science.1227775November 8, 2012
[font size=3] Hydrogen is an attractive fuel source because it can easily be converted into electric energy and gives off no greenhouse emissions. A group of chemists at the University of Rochester is adding to its appeal by increasing the output and lowering the cost of current light-driven hydrogen-production systems.
The work was done by graduate students Zhiji Han and Fen Qiu, as part of a collaboration between chemistry professors Richard Eisenberg, Todd Krauss, and Patrick Holland, which is funded by the U.S. Department of Energy. Their paper will be published later this month (Nov. 23) in the journal Science.
The chemists say their work advances what is sometimes considered the "holy grail" of energy science—efficiently using sunlight to provide clean, carbon-free energy for vehicles and anything that requires electricity.
One disadvantage of current methods of hydrogen production has been the lack of durability in the light-absorbing material, but the Rochester scientists were able to overcome that problem by incorporating nanocrystals. "Organic molecules are typically used to capture light in photocatalytic systems," said Krauss, who has been working in the field of nanocrystals for over 20 years. "The problem is they only last hours, or, if you're lucky, a day. These nanocrystals performed without any sign of deterioration for at least two weeks."
…[/font][/font]
