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OKIsItJustMe

(19,938 posts)
Fri Nov 18, 2016, 06:23 PM Nov 2016

New Study Explains Mysterious Source of Greenhouse Gas Methane in the Ocean

http://www.whoi.edu/news-release/mysterious-methane-in-the-ocean
[font face=Serif][font size=5]New Study Explains Mysterious Source of Greenhouse Gas Methane in the Ocean[/font]


The new study determined that much of the ocean’s dissolved organic matter is made up of novel polysaccharides—long chains of sugar molecules created by photosynthetic bacteria in the upper ocean. Bacteria begin to slowly break these polysaccharides, tearing out pairs of carbon and phosphorus atoms from their molecular structure. In the process, the microbes create methane, ethylene, and propylene gasses as byproducts. Most of the methane escapes back into the atmosphere. (Illustration by Eric Taylor, Woods Hole Oceanographic Institution)

November 17, 2016

[font size=3]For decades, marine chemists have faced an elusive paradox. The surface waters of the world’s oceans are supersaturated with the greenhouse gas methane, yet most species of microbes that can generate the gas can’t survive in oxygen-rich surface waters. So where exactly does all the methane come from? This longstanding riddle, known as the “marine methane paradox,” may have finally been cracked thanks to a new study from the Woods Hole Oceanographic Institution (WHOI).

According to WHOI geochemist Dan Repeta, the answer may lie in the complex ways that bacteria break down dissolved organic matter, a cocktail of substances excreted into seawater by living organisms.

In a paper released in the November 14, 2016 issue of the journal Nature Geoscience, Repeta and colleagues at the University of Hawaii found that much of the ocean’s dissolved organic matter is made up of novel polysaccharides—long chains of sugar molecules created by photosynthetic bacteria in the upper ocean. Bacteria begin to slowly break these polysaccharides, tearing out pairs of carbon and phosphorus atoms (called C-P bonds) from their molecular structure. In the process, the microbes create methane, ethylene, and propylene gasses as byproducts. Most of the methane escapes back into the atmosphere.

“All the pieces of this puzzle were there, but they were in different parts, with different people, in different labs, at different times,” says Repeta. “This paper unifies a lot of those observations.”

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New Study Explains Mysterious Source of Greenhouse Gas Methane in the Ocean (Original Post) OKIsItJustMe Nov 2016 OP
For the layman... yallerdawg Nov 2016 #1
Not simple polysaccharides 4dog Nov 2016 #2
Interesting! Apparently, those really are C-P bonds, which were thought to be very rare ... eppur_se_muova Nov 2016 #3

4dog

(505 posts)
2. Not simple polysaccharides
Fri Nov 18, 2016, 07:38 PM
Nov 2016

like starch or cellulose, which have no P. Will add more if I have time to read original.

eppur_se_muova

(36,289 posts)
3. Interesting! Apparently, those really are C-P bonds, which were thought to be very rare ...
Tue Nov 22, 2016, 07:59 PM
Nov 2016

in living organisms.

Perhaps there's some "Arbuzovase" enzyme waiting to be discovered ?

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