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MindMover

(5,016 posts)
Sun Apr 27, 2014, 07:34 PM Apr 2014

The Forever Battery

Imergy Power Systems’ headquarters in an office park in one of Silicon Valley’s less glamorous precincts is the type of place where the future used to be invented. There are no Beats headphones-wearing 20-somethings on scooters. No foosball tables, rooftop beer garden or ironically named conference rooms. No birdhouses. Just a sea of drab, blue-gray cubicles. The median employee age appears to be around that of the typical software engineer who files an age-discrimination lawsuit. There are scientists wearing white lab coats. Some have white hair. The chief executive is 61 – that’s 120 in Silicon Valley years.

Needless to say, Imergy is not developing the next $19 billion app that Facebook will acquire, but the startup could end up powering Facebook.

"Basically, our battery lasts forever."

Imergy has spent years perfecting an energy storage device that, if it lives up to its billing, will help accelerate the big green future by allowing companies and homeowners to pull the plug on their local utility by banking electricity from solar arrays and wind farms for use when the sun is not shining or the wind is not blowing. A 250-kilowatt battery system installed in a 40-foot container, for instance, could store solar energy from the rooftop arrays of a 40-home neighborhood for later use.

This magic box is called a Vanadium redox flow battery. The heart of a flow battery are two electrolyte solutions – one positive, one negative – contained in separate tanks. When the solutions are pumped through a power cell containing a membrane, a chemical reaction takes place that generates electricity. When the process is reversed, the electrolyte stores energy.

http://www.theatlantic.com/technology/archive/2014/04/the-forever-battery/361167/

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14 replies = new reply since forum marked as read
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The Forever Battery (Original Post) MindMover Apr 2014 OP
Interesting Cirque du So-What Apr 2014 #1
Can't wait to fight wars over Vanadium! jberryhill Apr 2014 #2
I am skeptical. longship Apr 2014 #3
The physics of the battery have been proven. And the batteries do, in fact, exist... Gravitycollapse Apr 2014 #5
That's the problem with batteries. longship Apr 2014 #7
Do you know of any contamination issues? oldhippie Apr 2014 #8
I would have been less skeptical if ...... oldhippie Apr 2014 #6
This is really not that big a deal, just a solution cell, not revolutionary. eppur_se_muova Apr 2014 #13
Thank you very much for the info. longship Apr 2014 #14
The electrolyte is a dangerously acidic liquid and has to be cooled to 131 degrees or less... Gravitycollapse Apr 2014 #4
most likely they would be Niceguy1 Apr 2014 #9
My house never gets above 88° even in summer Orrex Apr 2014 #10
I don't think the ambient temp ... oldhippie Apr 2014 #12
k&r Duppers Apr 2014 #11

Cirque du So-What

(25,939 posts)
1. Interesting
Sun Apr 27, 2014, 07:49 PM
Apr 2014

but after reading the article, I half-expect the reprehensible Kochs to launch a campaign against recovering vanadium from iron ore waste, oil sludge and fly ash - citing suddenly-developed environmental 'concerns.'

longship

(40,416 posts)
3. I am skeptical.
Sun Apr 27, 2014, 08:25 PM
Apr 2014

Battery advances are incremental, rarely revolutionary. If this is the real deal, it will have to go through some peer review.

I would like to read the science behind this and how it stacks up.

However, if this is the real deal, it looks very promising. That is, if it lives up to the media coverage.

We'll see.

Gravitycollapse

(8,155 posts)
5. The physics of the battery have been proven. And the batteries do, in fact, exist...
Sun Apr 27, 2014, 08:34 PM
Apr 2014

The problem is that this type of battery has many shortcomings which include the fact that it needs to be kept within a specific temperature range before it starts to degrade and the electrolyte is an extremely acidic liquid.

You can design containers that are extremely strong but the supposed futuristic exchange of charged electrolytes while withdrawing the spent liquid is going to be a problem because the average lay person won't be able to safely handle the liquid. Which makes it markedly more difficult, and thus more expensive, than pumping gas or even hydrogen.

longship

(40,416 posts)
7. That's the problem with batteries.
Sun Apr 27, 2014, 08:44 PM
Apr 2014

Storing energy is a real bitch. One has to fight thermodynamics, physics, chemistry, and it all has to have large storage (apparently good here), recharge cycles (also apparently good), cheap to build (uh oh), small (double uh oh), and a myriad of other things.

Battery tech advances are going to be incremental for the foreseen future. At least until we discover dilithium crystals and anti-matter energy. (But Captain! The dilithium crystals canno take it much longer!)

The best solution. Put billions into research on all of the above.

 

oldhippie

(3,249 posts)
8. Do you know of any contamination issues?
Sun Apr 27, 2014, 08:47 PM
Apr 2014

I haven't really looked at this technology yet, but I worked a bit in the development of direct methanol fuel cells, and contamination from the air and catalytic contamination were major issues. Things worked well in the lab, but when you took them out into *real* air there were issues. The issues were solved, somewhat, but still affect the maintenance and useful life of a system.

 

oldhippie

(3,249 posts)
6. I would have been less skeptical if ......
Sun Apr 27, 2014, 08:42 PM
Apr 2014

... the article hadn't said, "A 250-kilowatt battery system ... ." Yeah, I know it's probably just the "journalist" doesn't understand the terms, but still .....

I, too, hope that it works. But I notice the article has the " ...if it lives up to its billing," caveat.

(sigh) I really want to believe in these breakthroughs, but I've been watching them come out now for almost 50 years.

You're right - we'll see.

eppur_se_muova

(36,263 posts)
13. This is really not that big a deal, just a solution cell, not revolutionary.
Mon Apr 28, 2014, 07:46 PM
Apr 2014

The science was worked out decades ago -- take second semester General Chemistry and you'll know more about this device than what you'll find in the science "journalism" stories on this topic. There appears to be no *really* new technology involved (membrane cells have been around for a while), though you won't find the details in this drive-by reportage. It *is* an incremental improvement over other storage batteries, such as lead-acid, but revolutionary -- no, not without a fairly generous definition of that term. It is a business opportunity, not a world-changer.

Because it uses solutions rather than pure liquids or solids, it is much too bulky and heavy for portable uses. Also, vanadium is much higher atomic weight than lithium, so that adds to the weight. The "non-toxic electrolyte" is apparently sulfuric acid -- which doesn't stop proponents from dismissing lithium (once an ingredient in 7-Up) in competing technologies as "toxic". Oh, and both redox reactions are one-electron processes -- a two-electron process would halve the amount of solute required, all other things being equal (an important qualifier).

"two solutions, one positive, one negative ..." Barf. OK, not everyone stuck through the second semester, but that's still horribly inaccurate descriptive writing. In fact, one side of the cell uses the V(V)/V(IV) couple, the other V(III)/V(II). The advantage of this setup is that both reactants and products in both sides of the cell are in solution -- no solids, which leads to complications which limit the lifetime of lead-acid, lithium, NiCd, etc. cells. If the two solutions don't mix, there's no need to use the same element on both sides -- I don't know if there's a compelling reason for it in this device, but there's a good chance these two couples aren't the only ones that work well. After all, the Periodic Table has a little something in it for everybody.

It's worth noting that these cells have been in commercial use since 2000, and they haven't shaken the ground under anyone's feet, as far as I can tell.

longship

(40,416 posts)
14. Thank you very much for the info.
Mon Apr 28, 2014, 10:00 PM
Apr 2014

I was educated in physics, but have some chemistry, too, most of which I have forgotten.

Your post brought back some memories.

A great response, BTW.

Best regards.

Gravitycollapse

(8,155 posts)
4. The electrolyte is a dangerously acidic liquid and has to be cooled to 131 degrees or less...
Sun Apr 27, 2014, 08:29 PM
Apr 2014

Somehow I don't see this becoming a truly viable option for most consumer markets.

 

oldhippie

(3,249 posts)
12. I don't think the ambient temp ...
Sun Apr 27, 2014, 10:54 PM
Apr 2014

... is what they are worried about. It's more likely about cooling the power cell/reaction chamber when it is pumping out 250 kW.

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