http://www.sciencedaily.com/releases/2005/12/051202085309.htm The world's largest mass extinction was probably caused by poisonous volcanic gas, according to research published today...........snip
Many scientists had previously thought that an asteroid hitting the earth or a deep-sea methane release had caused the extinction, which obliterated more than two-thirds of reptile and amphibian families.
However, analysis of a unique set of molecules found in rocks taken from the Dolomites in Italy has enabled scientists to build up a picture of what actually happened. The molecules are the remains of polysaccharides, large sugar-based structures common in plants and soil, and they tell the story of the extinction...............snip
The researchers believe that the volcanic gases from the eruption, which would have depleted earth's protective ozone layer and acidified the land and sea, killed rooted vegetation. This meant that soil was no longer retained and it washed into the surrounding oceans.