Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturingStephen G. Osborna, Avner Vengoshb, Nathaniel R. Warnerb, and Robert B. Jacksona,b,c,1
aCenter on Global Change, Nicholas School of the Environment, bDivision of Earth and Ocean Sciences, Nicholas School of the Environment, and cBiology Department, Duke University, Durham, NC 27708
Edited* by William H. Schlesinger, Cary Institute of Ecosystem Studies, Millbrook, NY, and approved April 14, 2011 (received for review January 13, 2011)
Abstract
Directional drilling and hydraulic-fracturing technologies are dra- matically increasing natural-gas extraction. In aquifers overlying the Marcellus and Utica shale formations of northeastern Pennsyl- vania and upstate New York, we document systematic evidence for methane contamination of drinking water associated with shale- gas extraction. In active gas-extraction areas (one or more gas wells within 1 km), average and maximum methane concentrations in drinking-water wells increased with proximity to the nearest gas well and were 19.2 and 64 mg CH4 L␣1 (n 26), a potential explosion hazard; in contrast, dissolved methane samples in neigh- boring nonextraction sites (no gas wells within 1 km) within similar geologic formations and hydrogeologic regimes averaged only 1.1 mg L␣1 (P < 0.05; n 34). Average à13 C-CH4 values of dissolved methane in shallow groundwater were significantly less negative for active than for nonactive sites (␣37`7‰ and ␣54`11‰, respectively; P < 0.0001). These à13C-CH4 data, coupled with the ra- tios of methane-to-higher-chain hydrocarbons, and à2 H-CH4 values, are consistent with deeper thermogenic methane sources such as the Marcellus and Utica shales at the active sites and matched gas geochemistry from gas wells nearby. In contrast, lower-concentra- tion samples from shallow groundwater at nonactive sites had isotopic signatures reflecting a more biogenic or mixed biogenic/ thermogenic methane source. We found no evidence for contam- ination of drinking-water samples with deep saline brines or frac- turing fluids. We conclude that greater stewardship, data, and— possibly—regulation are needed to ensure the sustainable future of shale-gas extraction and to improve public confidence in its use.
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Methane concentrations were detected generally in 51 of 60 drinking-water wells (85%) across the region, regardless of gas industry operations, but concentrations were substantially higher closer to natural-gas wells (Fig. 3). Methane concentrations were 17-times higher on average (19.2 mg CH4 L␣1) in shallow wells from active drilling and extraction areas than in wells from nonactive areas (1.1 mg L␣1 on average; P < 0.05; Fig. 3 and Table 1). The average methane concentration in shallow ground- water in active drilling areas fell within the defined action level (10–28 mgL␣1) for hazard mitigation recommended by the US Office of the Interior (13), and our maximum observed value of 64 mg L␣1 is well above this hazard level (Fig. 3). Understanding the origin of this methane, whether it is shallower biogenic or deeper thermogenic gas, is therefore important for identifying the source of contamination in shallow groundwater systems....
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