http://web.mit.edu/newsoffice/2009/nanotubes-0810.html Researchers make carbon nanotubes without metal catalyst
Oxides, as well as metals, seem to be able to sprout carbon nanotubes, study finds
Kate Greene, News Office correspondent
August 10, 2009
Carbon nanotubes - tiny, rolled-up tubes of graphite - promise to add speed to electronic circuits and strength to materials like carbon composites, used in airplanes and racecars. A major problem, however, is that the metals used to grow nanotubes react unfavorably with materials found in circuits and composites. But now, researchers at MIT have for the first time shown that nanotubes can grow without a metal catalyst. The researchers demonstrate that zirconium oxide, the same compound found in cubic zirconia "fake diamonds," can also grow nanotubes, but without the unwanted side effects of metal.
The implications of ditching metals in the production of carbon nanotubes are great. Historically, nanotubes have been grown with elements such as iron, gold and cobalt. But these can be toxic and cause problems in clean room environments. Moreover, the use of metals in nanotube synthesis makes it difficult to view the formation process using infrared spectroscopy, a challenge that has kept researchers in the dark about some of the aspects of nanotube growth.
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The findings are already impressing researchers in industry. "This innovation has far-reaching implications for commercial productions of carbon nanotubes," says David Lashmore, CTO of Nanocomp Technologies Inc., a company in Concord, N.H., that was not involved in the research. "It for the first time allows the use of a ceramic catalyst instead of a magnetic transition metal, some of which are carcinogenic."
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